Volume 34
Main Index

Issue 01

Photoinduced Ortho [2 + 2] Cycloaddition of Double Bonds to Triplet Benzenes Peter J. Wagner pp 1–8 DOI: 10.1021/ar000113n

Photoresponsive Polypeptides Osvaldo Pieroni, Adriano Fissi, Nicola Angelini, and Francesco Lenci pp 9–17 DOI: 10.1021/ar990141+

The Development of L2X2RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story Tina M. Trnka and Robert H. Grubbs pp 18–29 DOI: 10.1021/ar000114f

Bichromophoric Paracyclophanes:  Models for Interchromophore Delocalization Glenn P. Bartholomew and Guillermo C. Bazan pp 30–39 DOI: 10.1021/ar9901568

Mimicking Photosynthetic Solar Energy Transduction Devens Gust, Thomas A. Moore, and Ana L. Moore pp 40–48 DOI: 10.1021/ar9801301

Pyridoxal 5‘-Phosphate-Dependent α,β-Elimination Reactions:  Mechanism of O-Acetylserine Sulfhydrylase Chia-Hui Tai and Paul F. Cook pp 49–59 DOI: 10.1021/ar990169l

Structure−Property Relationships in Dendritic Encapsulation Christopher B. Gorman and Jennifer C. Smith pp 60–71 DOI: 10.1021/ar000044c

Elucidating the Nature of Enzyme Catalysis Utilizing a New Twist on an Old Methodology:  Quantum Mechanical−Free Energy Calculations on Chemical Reactions in Enzymes and in Aqueous Solution Peter A. Kollman, Bernd Kuhn, Oreola Donini, Mikael Perakyla, Rob Stanton, and Dirk Bakowies pp 72–79 DOI: 10.1021/ar000032r

Aufbau Principle of Complex Open-Framework Structures of Metal Phosphates with Different Dimensionalities C. N. R. Rao, Srinivasan Natarajan, Amitava Choudhury, S. Neeraj, and A. A. Ayi pp 80–87 DOI: 10.1021/ar000135+

Issue 02

Recent Highlights in Hemicarcerand Chemistry Ralf Warmuth, Juyoung Yoon pp 95–105 DOI: 10.1021/ar980082k

Metric Engineering of Soft Molecular Host Frameworks K. Travis Holman, Adam M. Pivovar, Jennifer A. Swift, and Michael D. Ward pp 107–118 DOI: 10.1021/ar970272f

Copper Delivery by Metallochaperone Proteins Amy C. Rosenzweig pp 119–128 DOI: 10.1021/ar000012p

Substituent Effects on the Reactivity of the Silicon−Carbon Double Bond Tracy L. Morkin and William J. Leigh pp 129–136 DOI: 10.1021/ar960252y

Is the CO Adduct of Myoglobin Bent, and Does It Matter? Thomas G. Spiro and Pawel M. Kozlowski pp 137–144 DOI: 10.1021/ar000108j

The Crotonase Superfamily:  Divergently Related Enzymes That Catalyze Different Reactions Involving Acyl Coenzyme A Thioesters Hazel M. Holden, Matthew M. Benning, Toomas Haller, and John A. Gerlt pp 145–157 DOI: 10.1021/ar000053l

Dynamics of Photoinduced Charge Transfer and Hole Transport in Synthetic DNA Hairpins Frederick D. Lewis, Robert L. Letsinger, and Michael R. Wasielewski pp 159–170 DOI: 10.1021/ar0000197

Model Studies for Molecular Recognition of Carbonic Anhydrase and Carboxypeptidase Eiichi Kimura pp 171–179 DOI: 10.1021/ar000001w

Issue 03

Dendrimer-Encapsulated Metal Nanoparticles:  Synthesis, Characterization, and Applications to Catalysis Richard M. Crooks, Mingqi Zhao, Li Sun, Victor Chechik, and Lee K. Yeung pp 181–190 DOI: 10.1021/ar000110a

Molecular Sieve Catalysts for the Regioselective and Shape- Selective Oxyfunctionalization of Alkanes in Air John Meurig Thomas, Robert Raja, Gopinathan Sankar, and Robert G. Bell pp 191–200 DOI: 10.1021/ar970020e

Is Water a Friend or Foe in Organometallic Chemistry? The Case of Group 13 Organometallic Compounds† Herbert W. Roesky, Mrinalini G. Walawalkar and Ramaswamy Murugavel pp 201–211 DOI: 10.1021/ar0001158

Experimental Strategies for Combinatorial and High-Throughput Materials Development James N. Cawse pp 213–221 DOI: 10.1021/ar000117s

Behavioral Patterns of Heterometallic Cuboidal Derivatives of [M3Q4(H2O)9]4+ (M = Mo, W; Q = S, Se) Rita Hernandez-Molina, Maxim N. Sokolov, and A. Geoffrey Sykes pp 223–230 DOI: 10.1021/ar960152s

Molecule-Mimetic Chemistry and Mesoscale Self-Assembly Ned B. Bowden, Marcus Weck, Insung S. Choi, and George M. Whitesides pp 231–238 DOI: 10.1021/ar0000760

New Materials in Hydrothermal Synthesis Shouhua Feng and Ruren Xu pp 239–247 DOI: 10.1021/ar0000105

Formation of Novel Polymeric Nanoparticles Guangzhao Zhang, Aizhen Niu, Shufu Peng, Ming Jiang, Yingfeng Tu, Mei Li, and Chi Wu pp 249–256 DOI: 10.1021/ar000011x

Issue 04

Some Interesting Properties of Metals Confined in Time and Nanometer Space of Different Shapes Mostafa A. El-Sayed pp 257–264 DOI: 10.1021/ar960016n

Subpicosecond Solvent Dynamics in Charge-Transfer Transitions:  Challenges and Opportunities in Resonance Raman Spectroscopy Jeanne L. McHale pp 265–272 DOI: 10.1021/ar000007l

Theoretical Perspectives on Proton-Coupled Electron Transfer Reactions Sharon Hammes-Schiffer pp 273–281 DOI: 10.1021/ar9901117

Multiple Isotope Effects on the Acyl Group Transfer Reactions of Amides and Esters John F. Marlier pp 283–290 DOI: 10.1021/ar000054d

The Quantum World of Cold Electron Collisions David Field, Stuart L. Lunt, and Jean-Pierre Ziesel pp 291–298 DOI: 10.1021/ar0000962

Substrate Dehydrogenation by Flavoproteins Paul F. Fitzpatrick pp 299–307 DOI: 10.1021/ar0000511

Homogeneous Single-Component Betaine Ziegler−Natta Catalysts Derived from (Butadiene)zirconocene Precursors Gerhard Erker pp 309–317 DOI: 10.1021/ar9800183

Modular Chemistry:  Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks Mohamed Eddaoudi, David B. Moler, Hailian Li, Banglin Chen, Theresa M. Reineke, Michael O'Keeffe, and Omar M. Yaghi pp 319–330 DOI: 10.1021/ar000034b

Issue 05

The Reaction of Cl with CH4:  A Connection between Kinetics and Dynamics Hope A. Michelsen pp 331–337 DOI: 10.1021/ar000066z

The Central Enzymes of the Aspartate Family of Amino Acid Biosynthesis Ronald E. Viola pp 339–349 DOI: 10.1021/ar000057q

Large-Scale ab Initio Quantum Chemical Calculations on Biological Systems Richard A. Friesner and Barry D. Dunietz pp 351–358 DOI: 10.1021/ar980111r

Synthetic Chemistry for Ultrapure, Processable, and High-Mobility Organic Transistor Semiconductors Howard E. Katz, Zhenan Bao, and Sylvain L. Gilat pp 359–369 DOI: 10.1021/ar990114j

Electrochemical Nanostructuring with Ultrashort Voltage Pulses Viola Kirchner, Xinghua Xia, and Rolf Schuster pp 371–377 DOI: 10.1021/ar000133p

NMR Relaxation Studies of the Role of Conformational Entropy in Protein Stability and Ligand Binding Martin J. Stone pp 379–388 DOI: 10.1021/ar000079c

Design in Topographical Space of Peptide and Peptidomimetic Ligands That Affect Behavior. A Chemist's Glimpse at the Mind−Body Problem Victor J. Hruby pp 389–397 DOI: 10.1021/ar990063q

Enzymology, Structure, and Dynamics of Acetohydroxy Acid Isomeroreductase Renaud Dumas, Valérie Biou, Frédéric Halgand, Roland Douce, and Ronald G. Duggleby pp 399–408 DOI: 10.1021/ar000082w

Issue 06

Molecular Machines Special Issue pp 409–409 DOI: 10.1021/ar0100881

Molecular Machines J. Fraser Stoddart pp 410–411 DOI: 10.1021/ar010084w

The Physics of Molecular Motors Carlos Bustamante, David Keller, and George Oster pp 412–420 DOI: 10.1021/ar0001719

Electronically Transduced Molecular Mechanical and Information Functions on Surfaces Andrew N. Shipway and Itamar Willner pp 421–432 DOI: 10.1021/ar000180h

Switching Devices Based on Interlocked Molecules Anthony R. Pease, Jan O. Jeppesen, J. Fraser Stoddart, Yi Luo, C. Patrick Collier, and James R. Heath pp 433–444 DOI: 10.1021/ar000178q

Artificial Molecular-Level Machines:  Which Energy To Make Them Work? Roberto Ballardini, Vincenzo Balzani, Alberto Credi, Maria Teresa Gandolfi, and Margherita Venturi pp 445–455 DOI: 10.1021/ar000170g

Cyclodextrin-Based Molecular Machines Akira Harada pp 456–464 DOI: 10.1021/ar000174l

On the Way to Rotaxane-Based Molecular Motors:  Studies in Molecular Mobility and Topological Chirality Christoph A. Schalley, Kaweh Beizai, and Fritz Vögtle pp 465–476 DOI: 10.1021/ar000179i

Shuttles and Muscles: Linear Molecular Machines Based on Transition Metals Jean-Paul Collin, Christiane Dietrich-Buchecker, Pablo Gaviña, Maria Consuelo Jimenez-Molero, and Jean-Pierre Sauvage pp 477–487 DOI: 10.1021/ar0001766

Molecular Machines Based on Metal Ion Translocation Valeria Amendola, Luigi Fabbrizzi, Carlo Mangano, and Piersandro Pallavicini pp 488–493 DOI: 10.1021/ar010011c

Positive Allosteric Systems Designed on Dynamic Supramolecular Scaffolds:  Toward Switching and Amplification of Guest Affinity and Selectivity Seiji Shinkai, Masato Ikeda, Atsushi Sugasaki, and Masayuki Takeuchi pp 494–503 DOI: 10.1021/ar000177y

In Control of Motion:  From Molecular Switches to Molecular Motors Ben L. Feringa pp 504–513 DOI: 10.1021/ar0001721

Progress toward a Rationally Designed Molecular Motor T. Ross Kelly pp 514–522 DOI: 10.1021/ar000167x

Issue 07

The Synthetic Potential of Phthalimide SET Photochemistry Ung Chan Yoon*, Patrick S. Mariano* pp 523–533 DOI: 10.1021/ar010004o

Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis Xiyan Lu, Chunming Zhang, and Zhenrong Xu pp 535–544 DOI: 10.1021/ar000253x

Studies of Polar Stratospheric Cloud Formation Anthony J. Prenni and Margaret A. Tolbert pp 545–553 DOI: 10.1021/ar950186k

Photoisomerization by Hula-Twist:  A Fundamental Supramolecular Photochemical Reaction Robert S. H. Liu pp 555–562 DOI: 10.1021/ar000165c

Designer Magnets Containing Cyanides and Nitriles Joel S. Miller and Jamie L. Manson pp 563–570 DOI: 10.1021/ar0000354

The Role of Synchrotron-Based Studies in the Elucidation and Design of Active Sites in Titanium−Silica Epoxidation Catalysts John Meurig Thomas and Gopinathan Sankar pp 571–581 DOI: 10.1021/ar010003w

Structural Elucidation of Microporous and Mesoporous Catalysts and Molecular Sieves by High-Resolution Electron Microscopy John Meurig Thomas, Osamu Terasaki, Pratibha L. Gai, Wuzong Zhou, and Jose Gonzalez-Calbet pp 583–594 DOI: 10.1021/ar970352j

Exploration of Fundamental and Synthetic Aspects of the Intramolecular 4 + 3 Cycloaddition Reaction Michael Harmata pp 595–605 DOI: 10.1021/ar000064e

Why Is It So Difficult To Simulate Entropies, Free Energies, and Their Differences? William P. Reinhardt, Mark A. Miller, and Lynn M. Amon pp 607–614 DOI: 10.1021/ar950181n

Issue 08

Stereoselective Total Synthesis of Axially Chiral Natural Products via Biaryl Lactones Gerhard Bringmann and Dirk Menche pp 615–624 DOI: 10.1021/ar000106z

Competitive Pathways via Nonadiabatic Transitions in Photodissociation David Conroy, Victor Aristov, Lin Feng, Andrei Sanov, and Hanna Reisler pp 625–632 DOI: 10.1021/ar970047y

Catalytic Functionalization of Arenes and Alkanes via C−H Bond Activation Chengguo Jia, Tsugio Kitamura, and Yuzo Fujiwara pp 633–639 DOI: 10.1021/ar000209h

1,1-Dimetallic Reagents for the Elaboration of Stereoselectively Di- or Trisubstituted Linear Substrates Jean F. Normant pp 640–644 DOI: 10.1021/ar000043k

Mass-Independent Isotopic Compositions in Terrestrial and Extraterrestrial Solids and Their Applications Mark H. Thiemens, Joel Savarino, James Farquhar, and Huiming Bao pp 645–652 DOI: 10.1021/ar960224f

The Gas-Phase Chemistry of Cyclodextrin Inclusion Complexes Carlito B. Lebrilla pp 653–661 DOI: 10.1021/ar980125x

Hexafluorobenzene Photochemistry:  Wellspring of Fluorocarbon Structures David M. Lemal pp 662–671 DOI: 10.1021/ar960057j

Chiral Studies across the Spectrum of Polymer Science Mark M. Green, Kap-Soo Cheon, Sung-Yun Yang, Ji-Woong Park, Susan Swansburg, and Weihong Liu pp 672–680 DOI: 10.1021/ar010009l

Cobalamin-Dependent Methyltransferases Rowena G. Matthews pp 681–689 DOI: 10.1021/ar0000051

Issue 09

Understanding the Phase-Dependent Reactivity of Chlorine Dioxide Using Resonance Raman Spectroscopy Philip J. Reid pp 691–698 DOI: 10.1021/ar010064u

The Formation of Nitriles in Hydrocarbon-Rich Atmospheres of Planets and Their Satellites:  Laboratory Investigations by the Crossed Molecular Beam Technique Ralf I. Kaiser, Nadia Balucani pp 699–706 DOI: 10.1021/ar000112v

A Mechanistic Investigation of Gelation. The Sol−Gel Polymerization of Precursors to Bridged Polysilsesquioxanes Kenneth J. Shea and Douglas A. Loy pp 707–716 DOI: 10.1021/ar000109b

One- vs Two-Photon Processes in the Photochemistry of 1,n-Dihaloalkanes Miguel A. Miranda, Julia Pérez-Prieto, Enrique Font-Sanchis, and J. C. Scaiano pp 717–726 DOI: 10.1021/ar000107r

Chemoselective Approaches to Glycoprotein Assembly Howard C. Hang and Carolyn R. Bertozzi pp 727–736 DOI: 10.1021/ar9901570

The Unique Chemistry of Hydrogen beneath the Surface:  Catalytic Hydrogenation of Hydrocarbons S. T. Ceyer pp 737–744 DOI: 10.1021/ar970030f

The Gif Paradox Pericles Stavropoulos, Remle Çelenligil-Çetin, and Amy E. Tapper pp 745–752 DOI: 10.1021/ar000100+

The Effect of Limited Monomer Solubility in Heterogeneous Step-Growth Polymerization Ying-Hung So pp 753–758 DOI: 10.1021/ar0100069

Issue 10

Supramolecular Arrays Based on Dimetal Building Units F. Albert Cotton, Chun Lin, and Carlos A. Murillo pp 759–771 DOI: 10.1021/ar010062+

A Mimicking Enzyme Analogue for Chemical Sensors Jyh-Myng Zen and Annamalai Senthil Kumar pp 772–780 DOI: 10.1021/ar000073n

Time Reversal and Molecular Properties Laurence D. Barron, A. David Buckingham pp 781–789 DOI: 10.1021/ar0100576

Follow the Protons:  A Low-Barrier Hydrogen Bond Unifies the Mechanisms of the Aspartic Proteases Dexter B. Northrop pp 790–797 DOI: 10.1021/ar000184m

Advances in Metal Chemistry of Quinonoid Compounds:  New Types of Interactions between Metals and Aromatics Arkadi Vigalok and David Milstein pp 798–807 DOI: 10.1021/ar970316k

Using Resonance Raman Spectroscopy To Examine Vibrational Barriers to Electron Transfer and Electronic Delocalization Joseph T. Hupp and Robert D. Williams pp 808–817 DOI: 10.1021/ar9602720

Investigations of the Roles of the Distal Heme Environment and the Proximal Heme Iron Ligand in Peroxide Activation by Heme Enzymes via Molecular Engineering of Myoglobin Shin-ichi Ozaki, Mark P. Roach, Toshitaka Matsui, and Yoshihito Watanabe pp 818–825 DOI: 10.1021/ar9502590

Solid-Phase Syntheses of β-Turn Analogues To Mimic or Disrupt Protein−Protein Interactions Kevin Burgess pp 826–835 DOI: 10.1021/ar9901523

Targeting RNA with Small-Molecule Drugs:  Therapeutic Promise and Chemical Challenges José Gallego and Gabriele Varani pp 836–843 DOI: 10.1021/ar000118k

Issue 11

Chirality Transfer in Ferroelectric Liquid Crystals Robert P. Lemieux pp 845–853 DOI: 10.1021/ar9901164

Self-Assembled Monolayers of 4-Mercaptobiphenyls Abraham Ulman pp 855–863 DOI: 10.1021/ar0001564

Molecular Design of Artificial Molecular and Ion Recognition Systems with Allosteric Guest Responses Masayuki Takeuchi, Masato Ikeda, Atsushi Sugasaki, and Seiji Shinkai pp 865–873 DOI: 10.1021/ar0000410

Persulfoxide:  Key Intermediate in Reactions of Singlet Oxygen with Sulfides Edward L. Clennan pp 875–884 DOI: 10.1021/ar0100879

Attractive Intramolecular Edge-to-Face Aromatic Interactions in Flexible Organic Molecules W. Brian Jennings, Brid M. Farrell, and John F. Malone pp 885–894 DOI: 10.1021/ar0100475

Wide Bite Angle Diphosphines:  Xantphos Ligands in Transition Metal Complexes and Catalysis Paul C. J. Kamer, Piet W. N. M. van Leeuwen, and Joost N. H. Reek pp 895–904 DOI: 10.1021/ar000060+

Ruthenium Polypyridine Complexes. On the Route to Biomimetic Assemblies as Models for the Photosynthetic Reaction Center Heinz Dürr and Stefan Bossmann pp 905–917 DOI: 10.1021/ar9901220

Designer Hybrid Cyclopeptides for Membrane Ion Transport and Tubular Structures Darshan Ranganathan pp 919–930 DOI: 10.1021/ar000147v

Issue 12

Solvent Size vs Cohesive Energy as the Origin of Hydrophobicity Themis Lazaridis pp 931–937 DOI: 10.1021/ar010058y

The Depth of Chemical Time and the Power of Enzymes as Catalysts Richard Wolfenden and Mark J. Snider pp 938–945 DOI: 10.1021/ar000058i

Chiral Autocatalysis, Spontaneous Symmetry Breaking, and Stochastic Behavior Dilip K. Kondepudi and Kouichi Asakura pp 946–954 DOI: 10.1021/ar010089t

Dual Enantioselective Control in Asymmetric Synthesis Yong Hae Kim pp 955–962 DOI: 10.1021/ar000187z

Teaching Old Indicators New Tricks Sheryl L. Wiskur, Hassan Ait-Haddou, John J. Lavigne, and Eric V. Anslyn pp 963–972 DOI: 10.1021/ar9600796

Polymerized Lyotropic Liquid Crystal Assemblies for Materials Applications Douglas L. Gin, Weiqiang Gu, Bradford A. Pindzola, and Wen-Jing Zhou pp 973–980 DOI: 10.1021/ar000140d

Formation and Stability of Carbocations and Carbanions in Water and Intrinsic Barriers to Their Reactions John P. Richard, Tina L. Amyes, and Maria M. Toteva pp 981–988 DOI: 10.1021/ar0000556

Sapphyrins:  Versatile Anion Binding Agents Jonathan L. Sessler and Julian M. Davis pp 989–997 DOI: 10.1021/ar980117g

Poly(p-phenyleneethynylene)s by Alkyne Metathesis Uwe H. F. Bunz pp 998–1010 DOI: 10.1021/ar010092c